It was narrated from 'Aishah that:The Messeenger of Allah said: "Whoever catches one Rak'ah of the Subh before the sun rises, then he has caught it, and whoever catches one Rak'ah of the 'Asr before the sun sets, then he has caught it." (Sahih)Another chain with similar wording
Hadith No. 700
Sunan Ibn Majah
Gradings:
Al-Albani:
Sahih
Muhammad Fouad Abd al-Baqi:
Sahih
Shuaib Al Arnaut:
Sahih
Zubair Ali Zai:
Sahih Muslim